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Published Online: March 18 2007 | ss20070318a1
Keywords: InN | p-type semiconductor | Mg doping | solar cell

It's P

Lin PU
*

Laboratory fellows are the enemy of theory. Although so many times they work vainly, they indeed believe that everything is possible, if you do. For example, last year, we got the first fingerprint of p-type InN (1), which is in the same boat with GaN, AlN and ZnO hated by doping theory because of their valence band edges locating far below the Fermi level stabilization energy EFS, located 4.9 eV below the vacuum level (2).

1 2006 Jones RE et al., PRL 96, 125505.
2 2001 Walukiewicz W, Physica B 302, 123.
3 2004 Mahboob I et al., PRL 92, 036804.
4 2005 Li SX et al., PRB 71, 161201.
5 2007 Preuss P, Scidea Sketch, 1, ss20060331a1.
6 2007 Cao L, Scidea Sketch, 1, ss20060331a2.

Besides the valence band edge, the hinders in InN for p-type doping, such as low position of the conduction band edge and donorlike surface defects that prefer to pin the surface Fermi energy at EFS, also make a p-doping hard to be accessed (2, 3).

So when R. E. Jones et al. finally fulfilled this primary penetration in InN, by isolating the effects of the n-type conductivity in the surface accumulation layer with a rectifying contact to InN using an electrolyte (1), they justly feel happy, because "alloys of the two compounds (GaN & InN) could be combined to make a full-spectrum solar cell", reports Paul Preuss in this issue (5). 

However, the garden is full of stones. One such, for example, is just how to make a solid contact with other one, thinks Liang Cao (6). This longstanding problem surely links to the origin of the p-doing difficulty. If we can not bypass the barrier using liquid contact like that of PRL's report (1), what can we do?   

* Lin Pu is in the Physics Department of Nanjing University, Nanjing 210093, CHINA. 

 

Citation

Lin PU, It's P, Scidea Sketch 1 (3), ss20070318a1 (2007).
doi: 10.3128/ ss20070318a1 | Scidea ::  Abs . FullCrossRef
Scidea Sketch :: ISSN: 1992 - 8548    

 

Comments in this issue >>>>>>  

   

It's p-InN.
Scidea Sketch
March 16 2007 | ss20060331a2

Deep penetration


Liang CAO

 

Notes: It's p-InN.
 

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Full-spectrum solar cell
Editor: TOS
March 16 2007 | ss20060331a1

Conductivity is more than skin deep

Paul PREUSS

 

Now semiconductor indium nitride (InN) can conduct positive charges. For any other semiconductor the news would be unremarkable. But InN is one of the most frustrating, if most promising, of semiconductor materials.                          

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